Firstly, thanks for your comments.
Ok, I have not replied before as I wanted to be sure/check my answers before posting and I have now got the ISS down, so....
SIM in test mode (DIP Switch 4).
Off, in fact I have never changed any of the DIP switches from factory
SuperCap bad (or installed backwards or ....)
New SuperCap installed and correctly.
Battery low voltage when installed (or wrong kind of battery).
Battery obviously discharged now but is a 'branded' battery with date code of 2022. The spare one I had purchased at the same time tests good.
Bad "charging circuitry" in the SIM (i.e., failed diode, etc.)
This may be the answer. At the top of the ISS board above the power jack/solar connection there is a diode. It appears to be open circuit.
Any thoughts?