I think this is understood but let me just spell it out. To connect soil moisture and other soil (etc) temperature or leaf wetness sensors to a VP2 system then you must buy a 6345 multi-sensor transmitter, which is a different beast to the ISS transmitters and, as with every VP2 transmitter, must run on its own transmitter ID.
A single 6345 transmitter can be connected to (up to) 4 soil moisture sensors, 2 leaf wetness sensors and 4 temperature sensors. You need to purchase the 6345 transmitter and required sensors separately (other than the 6345CS bundle, but that would likely be overkill for any domestic installation). For best accuracy, the soil moisture reading needs to be temperature corrected and it's recommended that this is done by pairing each soil moisture sensor with a soil temperature sensor buried nearby and at the same depth as its paired soil moisture sensor. (Otherwise the ISS air temperature will be used AIUI, but that's obviously often different from the soil temperature.)
Don't be tempted to rush the installation of a new Watermark soil moisture sensor - for best results, it does need preliminary soaking as per the instructions. And also allow a few days for the sensor to bed into its new home before taking the readings too seriously. The sensor needs a little time to equilibrate fully with its surroundings, especially from new.
The 6100 WLL can receive data from ANY combination of up to 8 VP2 transmitters, so absolutely it can receive from an ISS plus a 6345 transmitter. A VP2 console can receive data from one ISS and one 6345, but no more. 6345 data is fully uploaded to weatherlink.com and can be viewed in the browser app in the usual way. Remember that 6345 temperature data received via a console will be truncated to a resolution of 1°F, but the same data received via a 6100 WLL will retain its full 0.1°F resolution.
I'm struggling to remember whether 6345 data via a 6100 shows up in the smartphone app - someone else may be able to chip in. IIRC this wasn't possible initially when the v2 app was first released, but may now have been added into the Additional Sensors section.