2 suggestions if you do this...
First, calibrate the car by timing while driving at a set speed between 2 or more mileposts on the highway, and calculating your speed. From
http://en.wikipedia.org/wiki/Speedometer:
"Speedometers are not totally accurate, and most speedometers have tolerances of some 10% plus or minus due to wear on tires as it occurs. Modern speedometers are said to be accurate within 10% but as this is legislated accuracy, this may not be entirely correct. This can make it difficult to accurately stay on the speed limits imposed; most countries allow for this known variance when using RADAR to measure speed, although levels of some 3 km/h or 3% are also used in areas of tough enforcement."
So, if your speed says 20 mph, you might be going as little at 18 or as much as 22 mpg.
Second, make sure the anemometer is held or mounted far enough away from the car that it's out of any slipstream that will make the speed appear greater. (Slipstream's not the right word, but you get the idea. It's too early for my brain to be fully warmed up.
)